It
will be the first time Iran - an ally of President Bashar al-Assad - has
attended such a summit with the US.
Representatives
of Russia, Saudi Arabia and Turkey will also attend the talks.
Earlier,
the US said an invitation had been extended to Iran - a move Syria's
Western-backed opposition questioned.
Meanwhile,
Russia said its aircraft had struck 118 "terrorist" targets in Syria
over a 24-hour period - a new record - as a result of what its defence ministry
said was new intelligence.
The
main round of talks on Syria is expected to take place on Friday, but diplomats
say some preparatory meetings could happen on Thursday evening.
"We
have reviewed the invitation, and it was decided that the foreign minister
would attend the talks," Iranian foreign ministry spokeswoman Marzieh
Afkham said.
Egypt
and Iraq also confirmed they had accepted invitations to the meeting.
BBC
diplomatic correspondent James Robbins says that while the US is certainly not
welcoming Iran to the Syria talks, it will now tolerate Tehran's involvement.
Iran's Fars news agency
said Mr Zarif had discussed participation in the Vienna talks with Russian
Foreign Minister Sergei Lavrov by phone on Tuesday.
Kremlin
spokesman Dmitry Peskov later told reporters that Russia wanted a
"widening of the dialogue" on Syria.
Iran
is believed to have spent billions of dollars over the past four years propping
up President Assad's government, providing military advisers and subsidising
weapons.
However,
Syria's political opposition has warned that Iran's involvement will only
complicate the meeting in Vienna.
Both
Iran and Russia - another ally of President Assad - have recently stepped up
their military role in the Syrian conflict.
Iran has long
acknowledged sending military advisers to Syria, but has denied the presence of
any ground forces.
Despite
that, unconfirmed reports earlier this month said that hundreds of Iranian
troops had arrived in Syria.
They
were reported to be joining government forces and fighters from the Lebanese
Shia Islamist movement, Hezbollah, in assaults on rebel positions in northern
and central Syria.
Russia
began its military intervention in Syria at the end of last month, launching
air strikes in support of President Assad.
Russia
and Iran have insisted that Mr Assad must be part of any transition government
and that the Syrian people must be allowed to decide who governs them.
The
US has indicated it could only tolerate President Assad during a short
transition period, after which he should step down.
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